I have 2 questions.
Is it possible to enable a license plan options in office 365 for all users through powershell.
i create a new tenant like email@example.com, and i have 250 users.
Is that possible to create a script or something
You can find answers to your first question with a simple web search: https://technet.microsoft.com/en-us/library/dn771770.aspx. The short answer is yes.
The second question is really a 'it depends'. If you have context that can be used to determine who would get a license, then you could certainly assign licenses dynamically based on title, department or if their first name is Henry. As long as you have criteria that can be logically defined, then you can script it.
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